Classification of Lubricants
Depending on their way of action, one distinguishes between internal and external lubricants, with continuous transition. Internal lubricants often exhibit a certain external lubrication and vice versa. Lubricants having both effects are called “combined”.
Internal lubricants reduce friction occuring between the molecular chains of PVC, thus lowering the melt viscosity. They are polar, highly compatible with PVC, give excellent transparency even in high dosages and do not tend to exudate which could impair the weldability, printability and bonding properties.
External lubricants mainly reduce wall adhesion between PVC and metal surfaces. Most of them are non-polar substances, such as paraffins or polyethylene. The external lubrication is influenced by the length of the hydrocarbon chain, the branching or the functional groups. In high dosages “over-lubrication” can lead to haziness and exudation. External lubricants increase the fusion time.
| Type | Baerolub | Chemical composition | Physical form | Melting [°C] | Lubrication |
| Solid fatty esters | L-MS | Glycerol partial ester of sturated fatty acids (glyceryl monostearate approx. 40 %) | Powder | 56 - 62 | Internal |
| Solid fatty esters | L-CD | Glycerol ester of sturated fatty acids (Castor oil, hydrogenated) | Powder | 84 - 88 | internal |
| Solid fatty esters | GTS | Glycerol ester of sturated fatty acids | Powder | 50 - 54 | Combined |
| Solid fatty esters | L-TP | Fatty alcohol phtalate | Powder | 46 - 50 | Internal |
| Solid fatty esters | L-PM | Fatty acid ester wax | Powder | 52 - 55 | Combined |
| Solid fatty esters | A275 | Fatty acid complex ester and fatty acid Calcium soap | Powder Pellets | 125 - 135 | Combined |
| Solid fatty esters | 43C | Fatty acid complex ester | Powder Pellets | 59 - 65 | Combined |
| Solid fatty esters | LS100 | Fatty acid complex ester | Powder Pellets | 58 - 65 | Combined |
| Liquid fatty acid esters | L-PL | Glycerol partial ester of unsaturated fatty acids (glyceryl mono/dioleate) | Liquid | liquid at room temp. | Internal |
| Liquid fatty acid esters | L-PK | Fatty acid ester | Liquid | liquid at room temp. | Combined |
| Solid hydrocarbons | L-KO | Synthetic paraffin wax | Powder | 100 - 105 | External |
| Solid hydrocarbons | L-KM | Paraffin wax | Powder | 54 - 56 | External |
| Solid hydrocarbons | PA-L | Polyethylene wax | Powder | 102 - 110 | External |
| Solid fatty acids, alcohol and amide | FTA | Mixture of fatty acids | Powder | 54 - 60 | External |
| Solid fatty acids, alcohol and amide | FTO | Mixture of hydroxy fatty acids | Powder | 70 - 80 | External |
| Solid fatty acids, alcohol and amide | L-OH | Mixture of fatty alcohols | Powder | 52 - 54 | Internal |
| Solid fatty acids, alcohol and amide | L-AK | Amide wax (N,N'-ethylene distearamide) | Powder | 138 - 144 | External |
| Metal soaps | Ceasit SW/PA | Calcium stearate | Powder | approx. 160 | Internal |
| Metal soaps | Zincum T | Zinc stearate | Powder | approx. 120 | External |